The best way of getting to Coron is by plane from Manila to Busuanga Airport. Several low cost Filipino air companies fly to Busuanga (Pal Express, Cebu Pacific and Zest Air). From the airport you can take a mini van to Coron town. It is possible to get to Coron by ferry from Manila, but the trip is more than 12 hours, and more expensive than the cheapest plane tickets. You can also get a ferry to Coron from El Nido.
The town of Coron has some basic hotels. Rooms tend to fill up, I recommend booking in advance.
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